Trouts right about the silicone, you need a nutral cure. If you have an acid evolving cure you will corrode you solder joints and if you assemble before full cure you will have a corrosive fog inside your light.
My LED’s are fitted with pan head M2 screws which are way to small for the slottted holes in the stars. I’ve adjusted the centres of these to 18mm so the screws positivly locate the stars and then fitted small fibre washers under each one. I to couldnt source fibre washers so had to make my own from some this insulating sheet.
I think you will struggle to source Cateye base plates anywhere, mine were brought several years ago and they just dont seem to be available anymore.
Tapping sizes for metric screws will be the size minus the pitch, so M2 is 0.4mm pitch so tapping size will be 1.6 mm.