It’s not *actually* possible to run higher pressure in the negative chamber than the positive, since they’re in equilibrium – As soon as the pressure in the negative chamber is greater than the positive side, the fork will get ‘sucked’ down, the positive air chamber decreases in size and the positive pressure therefore increases to match the negative pressure.
So yeah, if you put in more volume in the negative side, it’ll suck the fork down. But it should be possible to match the pressures without losing any travel.
It all becomes a bit moot as soon as sag becomes involved though.