De-gassing for a normal bleed is just when you take the syringe of fluid, close the stopper and draw the plunger out a bit. The resulting vacuum forces gases dissolves into the fluid to come out. You then get rid of the bubbles as you normally would and then resume.
Since my last post I’ve bled both of my brakes, did one de-gassed and then left the other as it was from the bottle. It seems that for Avid brakes (where you bleed by negative pressure) the de-gassing is worthwhile as when you’re bleeding the caliper/lever you need to pull on the plunger just as you would when de-gassing. If you haven’t de-gassed already you get those bubbles during the bleed anyway.