Try re-setting it real quick after it stops firing. It may be the thermostat on the output side. SO it fires up and gets hot, then at some point turns off and needs a manual re-set and then it works for another period. If it then runs for an hour sounds like it might be a wonky timer. Is the pressure over 1 bar all the time, have you tried to bleed the system and not topped it up through the filling loop. Wouldbe easier if it didnt fire at all . Not even certain if there is a pilot light with thermocouple on most combi’s. Mine uses a HT spark to fire the gas . Unfortunatly the coil could be overheating , or the plug overhetaing and not firing, then the safety cut outs will stop the gas. Could be dirty ionization probe or magic eye, although these tend to stop all firing until changed / cleaned.
Listen real carefully to your boiler . Is the pump on , is the fan on, firing sequence normally click click click on basic step programmer , fan on, click check with air preassure sensor, click click gas on louder clack as gas train opens, click click BBBzzzzzzzzzzzz spark plug arcing , whhooofff of gas igniting , click click, checking to see if there is a flame of correct combustion characturistics. Then you are on / off dependant on TRV’s and demand .