IME 65.5 seems to be as slack as you need for a balanced bike you still want to pedal up! Obviously it will need a steep seat tube 73-75 to go with it.
It does depend on the frame. In general terms if it already has a high BB and you jack it up further with a longer travel fork it will start to feel tall and unwieldy in tight switchbacks. If it has a slack seat tube about 72-71 degrees, you effectively tilt it further backward resulting in floppy steering and front wheel lift on seated climbs (if you stand and mash you won’t notice it) as you will be near enough sat over the back axle.
Depends how compromised it feels to you. Some people run massive forks in frames not designed for it and love it, compromises and all. 10-20 mm more on a modern progressive geometry frame often doesn’t make a massive noticeable difference.