We ride bits of it where it passes through the Tarentaise, most often the cracking singletrack down from the Col de l’Iseran to Val d’Isere (although you’d be riding UP that!). Be aware that some of the GR5 is inside the Vanoise national park where mountain biking is not allowed (although I’m told locally that in practise you won’t have any problems unless you’re there with 10 blokes on DH bikes hooning around).
Someone on here definitely has done the whole thing (maybe Sapaudia?)
Don’t know about memory map, but we bought the French equivalent (IGN Georando) with pretty much all of the French alps maps for about £35.