Its not only the anti freezing aspects but the corrosion protection that’s also important.
+1
It’s part of the reason for coolant needing to be changed every 2/3/5/10 years as part of the service schedule.
I did one of my cars and flushed it with a hosepipe connected into the thermostat housing with the bung in the block removed, it took a long time to run clear and so much crap came out (vomit emoji). Worryingly the liquid in the expansion tank wasn’t that bad.
But for a one-off top-up like the OP water does fine, distilled is better as tap water will use up some of the inhibitor as well as diluting it, but again a top up won’t hurt. Like oil, the wrong oil is bad, but not enough oil is far worse!
19 litres is insane
Mid / Rear engine cars need long pipes to the rad at the front, the little intake scoops at the back are usually just feeding the air intake or ancillary things like oil coolers, AC compressors, etc.
It’s one of the reasons the Rover K-series got such a bad reputation, the cooling loop was reversed so it would warmup quicker, which meant when the thermostat eventually opened it let in a slug of cold water which made the block/head contract and break the head gasket. The problems much worse in an Elise or MGF because there was a much bigger reservoir of cold coolant in the long pipes under the floor.