Open up the system control panel, click on Advanced System Settings, go to the Advanced tab if needed, and click on the Enviromental Variables button.
Scroll down the list of System variables, until you see Path, click on it, then edit.
There’ll be a job lot of text, separated by semi-colons.
Here’s mine below:
C:\Program Files (x86)\AMD APP\bin\x86_64;C:\Program Files (x86)\AMD APP\bin\x86;C:\Program Files (x86)\NVIDIA Corporation\PhysX\Common;%SystemRoot%\system32;%SystemRoot%;%SystemRoot%\system32\wbem;C:\Program Files\Common Files\Microsoft Shared\Windows Live;C:\Program Files (x86)\Common Files\Microsoft Shared\Windows Live;%SYSTEMROOT%\System32\WindowsPowerShell\v1.0;C:\Program Files (x86)\ATI Technologies\ATI.ACE\Core-Static; D:\crysis-2\bin32;C:\Program Files (x86)\Windows Live\Shared;C:\Program Files (x86)\PHP
You’ll want to look for the %SystemRoot% entries, and modify them to C:\Windows\System32 (or whetherever your System 32 dir is) or if they’re not present, add them.
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