I have loads now – vests, SS and LS, merino, blends (e.g. sportwool) and synthetic, all different types and brands. I’ve kept a few from when I was fatter, and have bought more now I’ve lost weight.
Cut is almost as important as material for me. Something figure hugging feels much warmer than something loose
Material weight also has an impact, obviously
I tend to wear merino for lower activity things. I also wear them for commuting as they don’t smell and it’s a shorter activity so I rarely get too sweaty. I do find they take a while to dry once wet
Synthetic is better for high output stuff, it dries out much quicker.
I’ve bought a Brynje mesh baselayer for a trip this weekend. Supposed to be warm, dry quick, and vent well. It’ll be low single figures celsius so I’m hoping this will do well