“Why couldn’t he have done everyone a favour and launched some of this nuclear waste into the asteroid belt?”
Others have already pointed out that putting nuclear waste on top of a rocket, which relies upon the controlled combustion of flammable liquefied gas and several hundred thousand moving parts of unproven reliability could end up scattering nuclear waste over a huge area if it goes bang – see Cosmos 1402 for what happens when a nuclear powerplant disintegrates upon re-entry.
Also, nuclear waste is very, very dense in comparison to volume (lead used to be uranium for example) and depending on the type of waste, it can be vitrified in molten glass. Nuclear storage sites are by necessity very large. You’ll need something like a Space Elevator before we can reliably move nuclear waste off planet.