Not sure on the specifics of your setup but split charge normally doesn’t use a switched live, rather a feed that is live when the alternator is charging. Otherwise you could have your ignition in the ACC position and the batteries will be connected but the engine not running.
When I did a van conversion years ago I used a voltage sensing relay to provide the switch signal rather than having to find the alternator wire.
My new (to me) prado has a second battery, that uses a DC-DC charger, it was fitted by the previous owner and I wasn’t even aware such things existed until I found the battery and charger in the engine bay, no idea how this setup works!