I’ve used Vibram 5-Fingers, Freet and some of Merrell’s minimalist shoes for hiking. I like the stability and feeling of connection, but on big days, minimalist cushioning on harder ground is an acquired taste, particularly at first. Also, quite a few minimalist shoes lack any sort of rock protection plate and standing hard on a really pointy rock can be exquisitely painful. Yes, focussing on the micro-details of every step can avoid this, but hey, I like to look at where I’m walking as well as, well, walking.
I don’t like full-on traditional walking boots, which feel clumsy and heavy, but something like inov-8’s running / hiking range is a good sort of middle point for me at least. Just enough cushioning to take the edge off, but still flexible and connected with good ground feel. I’ve done a lot of miles in a pair of the older Roclite mids – higher ankle cuff=less grit in shoe ime – and really like them. Also used the posh more boot-like boot, which is a bit more supportive etc, but very high volume.
Anyway, it’s very personal, I’d maybe start with something in the middle and if you like it, go more minimalist. It’s also a little dependent on conditions, Lakes/Peak rocky stuff is harder on your feet than rolling grassy trails.