No good for ladders although you can install additional protection. Although I would not advise putting a ladder off a bay roof even with protection (H&S stuff / disclaimer!)
Agree the window cleaner going on mine to clean the my roof light. Does make me nervous.
Depending on the size (particularly if it’s small) and complexity of the roof I would consider the EDPM option. Mine is done in one piece minimising the risk of roll joints.
Maybe look at a ballasted option to provide protection. I didn’t bother on mine but I did consider this approach. If you’re looking to place a ladder on it I would consider protection with both EDPM and a single ply system such as Sarna as mentioned.
Check you’ve no restrictions. Generally I would associate this “type of architecture” with a possible Listed Building. Check it’s not to avoid any unneccessary pain.