If it’s gradually getting slower then I’d look at;
1) run malwarebytes
2) look at what processes and services are running at any time
uninstall any software you haven’t used for a year.
and see what happens then.
Web pages are becoming ‘richer’/larger over time so even browsers are putting more load on cpu/memeory etc than they used to but for purely browsing I wouldn;t worry about changing OS to try and speed things up.
Having said that a clean install of Vista would probably make the biggest difference as it would get rid of accumulated crap from however many years you’ve been adding stuff to the original build.