EDIT: I think he meant rims that would make roadie wheels 29" in diameter, about 2" larger than they currently are?
no, the benifit of 29'ers is supposedly the better rolling over obstacles and lower rolling resistance due to the longer/narrower contact patch.
Even specialist roadies like triathletes/track riders/Time trial's only use 19mm tires so theres not much to be gained by going even narrower.
It would raise the front wheel furter, thereby making the riders less aerodynamic.
They weigh significantly (to a roadie) more, as the rims have to be stiffer and need more spokes.
The usual way for roadies to go it towards 650b (mtb sized) rims in order to get lower and therefore more aerodynamic.