Aren't kayaks waterproof btw ?
Yes, and? I'm trying to make a rack, not a cover (will cover them with a tarp to keep the UV off, which does damage them).
Don't know what you googled for, molgrips, I wasn't getting anything relevant with my searches. Not that making furniture is at all relevant either – thanks anyway.
Thanks for the helpful comments – pretty much confirms my thoughts. Had thought of getting all fancy with mitred joints, but it looks like straight cut butt joints and metal brackets will do the job. Is far more complex than it could be as I want to store them in the passage by the side of the house, but against the wall which is part of next door's garage, so don't really want to go drilling into that for support, hence "semi-freestanding".