My commute is the same length as yours, although not quite as hilly, and the vast majority of my running training is to or from work. You might not want to run to work straight off, but it’s the most efficient way of getting miles in. Does take a bit of planning in terms of making sure you have clothes etc in the right place, and does also help if you have a shower at work too. I’m also lucky to have a variety of transport options available
My usual schedule is:
Monday AM run in PM train home
Tuesday AM cycle in PM run home (bike stays locked at work)
Wednesday cycle both ways (on bike #2)
Thursday AM run in PM cycle home
Friday AM train in PM run home
That gives me ~80km of running and the same of cycling during the week for a time cost over pure cycling of about 2 hours.
My schedule also means that I have 36 hours recovery between runs. I can add length to runs if I want/need, depending on training schedule, or can train part-distance.
Might be worth thinking about, I am lucky that my run is ~70% off-road and I have good facilities and options.
Cheers, Rich