Anyone built a Li-Ion pack or bought one that can suggest a source and a reliable (safe!) charger?
I have – using cells taken from laptop batteries bought on ebay. I (think I) know what I'm doing though – if you have to ask on here, then I wouldn't really recommend DIY with LiIon cells given how dangerous they can be. A 4th for smudge.
If you're running 3 Crees from a 7.2V pack you presumably have a boost regulator (Maxflex?), in which case yes you can go to 10V, but that's the maximum voltage your pack can be. Typically a nominal 7.2V NiMH pack will start off at 8.4V. You could go to a 7 cell NiMH pack, nominal 8.4V, max 9.8V, but a nominal 9.6V NiMH pack with 8 cells would destroy your LEDs when fully charged at 11.2V. Alternatively a 2 cell LiIon, nominal 7.4V max 8.4V would be OK, but not a 3 cell one.