Look out for 2014 Giant TCR Composite 1 or 2. Both are 10sp, either Ultegra or 105 respectively, but don’t get swayed by 11sp and an inferior frame from a 2015 model at the same price.
You will struggle to get a decent Ultegra bike for <£1000, but it’s worth finding an extra £200 to get it. Even though 105 is great, and you won’t notice the difference when riding, you’ll always wish you had Ultegra.
Plus, whatever you buy, you’ll want to change the wheels within 5 minutes, So there’s another £300+. Basically, you need to spend £1500.
Bottom line, £1000 seems like enough to get a great carbon bike. But it’s not 😆