Just tap the wall gently with your hammer, it should be very obvious where the studs are. Once you've found one or two, the rest should be more or less equal distance.
Grrr….this never bloomin' works for me! I just hit and hope 😯 (I don't really)
Can't add much to ernie's advice, he's the resident chippy anyway. I'd say definitely nail the architraves. Skirting – different methods depending on the wall. Is this the room you chipboarded not so long ago? To be honest, I often use fixings and gripfill. If there's a few kinks in the wall, gripfill alone won't hold it.
Last piece of advice – do the architrave first! And start with the head (the bit that goes across the top).