Well really you need to think about a few key drivers:
What do you weigh?
What sort of terrain are you riding?
How do you ride? (Smooth or plough through things?)
You are right that you now have a bit more volume but you also have bit less side Wall thickness, the tyre will comply more at the same pressures than it did with a tube…
You might want to consider lowering pressures a bit more though, for more compliance from the tires hopefully giving more grip and a better ride, high pressures with tubes are all about avoiding pinched tube really, you don’t have tubes now so high pressures won’t really improve flat resistance very much.
as for rolling resistance, well you are using a Semi slick on the rear, how much better do you want it? Tire tread and profile have a far greater impact on rolling resistance than pressure alone, off road it could be argured a softer tire rolls “better” across the uneven terrain.
Obviously too low a pressure and you run the risk of unseating or “rolling” the tire off the rim, you hear people claim they go down to -15psi for DH, I doubt that would work for many people long term…
I’d recommend you take them to 5psi below their old normal pressure (when you used tubes) and try that out, knock them down in 5psi increments until you find a happy balance between ride, grip and rolling resistance then make a note… It takes a few trial rides to get a good idea of what you’re going to be happy with, Front and rear pressures don’t have to match either, I tend to have about 5psi less in the front myself.
Basically experiment, it’s quite suprising how low you can go, but that’s not always ideal.