My neighbour, a retired plumber, tells me that in the old days when people actually repaired things it was common to unbolt those rods that hold the sections of the heat exchanger together and then rebuild it with new gaskets. I’d have thought that if you did this with a similar attitude to doing a car cylinder head gasket you’d be OK. Ours used to weep water, which would hiss and fizz as it warmed up.
In the end though we decided to go for a new condensing boiler so we sold (with great sadness) our old Land Rover, a money pit, and turned it into a new boiler, which saved us about 30-40% on our gas consumption.
But go and ask on DIYnot.com, they will know better.