If they are the Doppio Air air spring like my old 02 Marathon S than it was really hard to set them up properly (3 different valves). I managed to do that but couldn’t find a sweet spot it was either xc hard and no dive or small bumps but going quick through the travel. Once nearly got it right, took the shock pump with me and went for a ride. The pressures from the manual didn’t work too well and I just experimented with different settings I would suggest You try that.
Depending what extras do You have with the SL, I had ECC 3, You might have ETA or TST. I just flicked them to the second setting which increased the compression damping and the forks were not blowing through the travel and had them fully open when needed.
My friend has some 66 SL with the Doppio Air cartridge and hers are working sweet as a nut, maybe Marzocchi managed to do a decent one eventually and I even managed to set them up to work properly.
Summing up. Doppio Air on older Marzocchi forks = pain in the ass 🙂