MF - mains pressure cylinder (unvented) or a heated thermal store will give mains pressure hot water.
Renton, if you are thinking of moving in a few years, will you get payback from spending £2000 + on a new boiler in 4 or 5 years? I would think not, despite what a lot of people would claim. The biggest way you can influence your fuel bills is how you use it. A 1 deg change on your thermostat can be a 10% fuel saving, turning it off when you got out, turning it down when you are busy, turning it off half an hour earlier when you go to bed etc.
I would give this advice to one of my customers if they were in this position, obviously can't comment on your particular installation, but there is something to be said for 'if it ain't broke, don't fix it'.
You could possibly fit a pump to boost your water pressure, radiators can be changed regardless of which boioler you use. Saying that the pipewrok that is supplying them has to be big enough to supply them with enough water. Mail me any queries if you like, think I posted my address earlier.
Oh and I would never advise one of my customers to have a combi, for some they are the only option, but if you have the room, and money go for unvented.