If its really horrid i’d suggest a slosh out with warm water just to remove the loose stuff, then soak over night in water/household bleach mix (just a little bit of bleach – its pretty strong stuff) the next morning bleach should have cleaned it up nicely.
Rinse out and if you really want you could clean out with either milton or sterident – but there should be no need.
In future rinse out with clean water after each use and store in the Freezer – a rinse out with Milton from time to time can only help aswell…
Be carefull with supermarket own-brand snyde ‘Milton’ tabs – they work great but might bleach your clothes, whereas proper Milton wont… my Mrs discovered this when washing out baby bottles in ASDA own brand ‘Milton’ – and splashed it down her skirt.