Thanks for replies thus far, in response to some of these:
oxym0r0n – Doesn’t happen in particular gears, randomly can be any. Mech not stiff
Rusty Mac – Bike is not left locked up so unlikely to be bashed
boriselbrus – Could be the freewheel, i whip that off and have a look, sounds clean though
Mark N – still got the old cassette and chain, was pretty much the same reason for replacing it in the first place
BigJohn – Have lubed, but didn’t clean it first, will try.
orena45 – This is possible, the old chain and cassette was pretty worn out and the chain did come off yesterday, i only have two front chainrings so the smaller does get a lot of use, but it does feel like it’s happening at the rear.