At that price if you’re ok with rim brakes you should get something ok.
Boardman Team Carbon road bikes were often bought on cycle to work and used very lightly – on eBay there are loads of those around £300-400. Most have 2×10 sram rival which I found really decent when I had one – actually hated moving to 105 Shimano on the bike I got after that. The Boardman Team road bike (alloy version) will also probably have been bike to worked in a lot of cases and should also be in budget.
Most Cannondale caad bikes are going to be out of your price range I reckon – the 9’s and 10’s all seem quite pricey.
The likes of the Allez/ Giant Defy have been sold in huge numbers so are probably a lot of what you will see. All solid – just buy on condition.
Cube road bikes have often been punted out heavily discounted on sale when I’ve looked – never bought one but probably worth a look too.