Surprisingly not with XTR and I assume it will be the same with the road system.
It shifts so fast on the front that it acts like just a rear change. If that makes sense.
It’s hard to explain, but it will shift the front and rear at the same time. This means that if you’re climbing a hill in the big ring and get to the top of the cassette ( big – big ) the next shift will be a synchro shift which will drop to the small on the front and simultaneously drop 3 or 4 on the back.
In reality this feels like the rear cassette just grew by another 4 sprockets.
You can do this under power. I’ve done it under max load off road and it didn’t complain.