As far as I know the Shimano DI2 parts only work in certain combinations, because they switched protocols and stuff as the technology “progressed”. It would have been nice if you could just wire things up and have them understand each other, but that is probably not the case.
So, as it stands, no hydraulics for 10 speed.
l.e: Oh, and there’s this gem: “Note: As of 8/3/14 firmware updates from Shimano remove the functionality between 6770 and 6870/9070 electronic components being used together. Some previous firmware versions allowed the below conversion to function without replacing the front derailleur, but firmware being installed as of 8/3/14 will irreversibly render such a mixed system dysfunctional. As of 8/3/14, a 6870 front and rear derailleur are both required to allow 6770 shift levers to work with an 11 speed cassette.”
http://fitwerx.com/converting-shimano-ultegra-6770-di2-to-11-speed/
l.l.e: Vaguely related – https://twitter.com/internetofshit