I get really bad nappy rash on hot rides, usually at the start of a nice alps holiday, I think salt from sweat and friction is the main problem for me. Chamois butter (non menthol) helps prevent for me and it’s very dependent on the liners I’m wearing – eg decathlon liners are a disaster for me despite being popular on here.
You say years old shorts – I’d try some new ones as if the liners have become rough with time that might be a contributing factor. Also try a different butt cream, or even none?
Also I try to only wash with simple soap, anything containing sodium laureth sulphate (almost everything) makes my skin dry and susceptible to this kind of thing.
Oh and I feel her pain. I wish I could post a picture of my baboon butt from last summer on the first day of my alps holiday, but I’d get banned. Aaaah sudocreme