Some cast iron vee blocks. (shop carefully as some of the ebay ones turn out to be tiny)
Clamp blocks to hold tubes in the vice.
Angle finder / protractor
http://www.stakesys.co.uk/product/angle_finder_3/
Dial angle gauge (dunno why but I tend to use this more than my digital one).
http://www.whiterosetools.com/Silverline-250471
Tube notcher and a pile of holesaws (when you get bored of filing)
http://www.stakesys.co.uk/product/sta155_hole_saw_tube_notcher/
Files – anything you can find. Ideally a small and big one in each of flat, half round and round. You are only filing stuff a few mm thick so actual grades not especially important provided they aren’t super coarse.
A couple of rolls of emery cloth (coarse and medium).
Word of caution – be very careful what you are starting 🙂 It won’t stop and the pile of tubes, tools and other stuff keeps on growing….