I’ve got to go get a bigger card before I can try anything.
The Edge will have internal memory that you can drop the Talky Toaster map into.
Garmin have some ridiculous licensing restrictions placed on their maps and if you bought the CityNav map on card it’ll be locked to that card and won’t work on if transferred to another (I bought one and came locked to a tiny, used 4Gb card). If you downloaded the Garmin map it will work off another card but is likely to be tied to your specific Edge 800.
That said, I believe that there is software available on the ‘net to unlock Garmin maps.
As far as I know, there’s no way of switching maps.
Not sure about the Edge series, but my Oregon allows the enabling & disabling of maps in Settings and I think (although I might be wrong) that you can overlay multiple maps.