Round here the deliveroo’s are all on E-MTB’s. I guess there’s a bit of an arms race in that to make any decent money you have to do more jobs than the next person otherwise the next job is already allocated by the time you get back into the town. So maybe that’s a local phenomenon.
As for the question, do cycle couriers still exist. Yes. used to use the motorbike ones all the time when working in TV, someone would always break something or need a spare and driving the van across London is basically writing off my morning/afternoon. So phoning the nearest shop, paying by CC and telling them a courier would collect it in 30 min was a massive time saver.
Biggest extravagance was getting some rolls of (posh tessa stuff) ducktape couriered to where I was. Biggest expense was a motorbike to Cheshire and back to deliver a lapel mic! I did once take a camera to Ft William personally as even in the absence of overtime the 45p/mile on that trip made it a good weekend!