Nest and WB Greenstar here too.
You might want to think about how you’re going to power the Nest, I found it to be a bit of a faff but I have a solution now. The thermostat part of it is obviously wireless from the boiler but it still needs a power supply. If you don’t have old thermostat wiring in place to power the Nest from the base unit then you need to use the USB power adapter. This is annoying as you can’t chase the cable from the back of a socket, as you need 12V, not 240V.
In the end I got sick of having the wire hanging loose down the wall so I fitted another socket the other side of the wall (behind a book shelf) and put the cable through the wall.
What has everyone else done? I also considered using a 12V light transformer but that seems overkill for such a small amount of power and also quite bulky.