AFAIK….
you won’t be able to install onto a blank drive using an upgrade copy as it’s only licensed and locked to upgrading an existing license.
Sounds like to do that you would need to install the previous OS then upgrade it, if your planning to use the new SSD as the main drive and copy stuff off the other one the removing it will make it easier to get the boot loader right to select the OS to boot from, if it finds multiple OS’s it will construct a boot loader for both of them (fairly sure) and get confused maybe. Plugging another drive in after and making sure the bios is set to launch your SSD first will mean it boots from that and you will be able to browse the other drive, copy off what you need and then do what you want to do with it.