Generally speaking, it’s not the same as doing it on a bike. You will usually have to remove part of the caliper. Which is just a couple of bolts, but on cars, where these things are subject to quite a lot of heat, they can be quite stubborn.
It’s not a ball ache of a job. But as an absolute novice, you might well spend 2 or 3 hours doing it. (possibly more if you have issues).
How old are the pads? For the price of them, I’d probably change them if I was going to have them out. Unless they’re relatively new.
I wouldn’t discourage doing it mind. I think it’s good to work on your own cars. And as experienced as they are, a time-pressed mechanic is likely to do the bare minimum. If a job’s worth doing…