Is the shed made of wood? if so I suspect its more likely some scroat sets fire to your shed than the fuel spontaneously ignites!
I think you misunderstand spontaneous.
When I do my fire fighting course (every couple of years) the only way they can light the diesel fo the simulated liquid fire is to warm the surface with a propane burner, usually for some time. Having said that, one it’s been burning a bit, it’s obviosully a lot more ready to re-ignite.
I’d just tell her indoors I’d used the diesel in the car, in fact I would actually use most of it in the car… (obviouslly I have a diesel car)
Oh and it’s not the hydrocarbons I’d worry about – it’s the biocides and additives.