A few yrs back we did a re-roof and used a foam, not sure which one though but the client had his own ecofit/insulation/heat recovery business and he also didn’t want the ceilings damaged inside. The fool had decorated the whole house then thought about insulating the roof and as it was a vaulted ceiling this was the best option and as the roof was in poor condition it was a 2 birds 1 stone.
Afaikr it didn’t have any bonding properties, but is breathable.
It went something like – strip roof, clean out between spars, lay a breathable membrane onto ceiling and over spars, lapping the edges, lay another membrane put pulled taut, felt and batten as normal, inject/spray or whatever the foam then re slate using the existing tile replacing any that were shot.