Short answer, yes. Long answer below.
Two things I would consider. The first is vital and that is the dew point. In cold humid conditions you are likely to get pretty close at this time of year. The cold metal will mean that you get condensation ruining the wet paint. If you store the frame inside first you should be ok. Also don’t do it first thing with a cold frame or late in the day when the temperature is dropping.
Paint generally doesn’t tend to like being applied below 10C unless it is designed for those temperatures. It slows down the rate of chemical reaction/solvent evaporation (delete as appropriate). With paints that rely purely on solvent evaporation it is less of an issue. Also once the frame has started to dry you can move it indoors to let it finish off once the worst of the solvent has gone. The frame temperature will matter as if it is cold it will be a huge heat sink.
A half decent rattle can should have application details on it. Maybe read some and see. Not really my area of paint knowledge.