I have never found the Airport express to be easy to use via Android. There are a few apps around that you could try but have you checked whether others are having the same problem with DS Audio? If so there may be hope of an update.
An alternative is to try swapping the airport express for a chromecast audio especially if they are still going for £15 from Currys and others. I don’t know whether it will easily stream from the NAS but this is likely an easier route than the airport express.
Sonos would do it but the price for a connect is ridiculous.
Raspberry pi can work but just isn’t in the same league of simplicity as these out of the box solutions. I have one, I rarely use it.