Seller can refund money through paypal and it only takes a couple of clicks, i think you still get charged the fees though. If you have to send the money through before you view the bike. I would advise you make the seller aware of this before you go and see the bike as if the money suddenly turns up he may simply think you have bought it before viewing and ar just going to pick it up.
Is there no way for you to take a laptop or something with you and ask to borrow the guys internet connection for a minute to transfer the money?
Ask if there is an internet cafee or a coffee shop with free wifi near by i think even the like of McDonalds do free wifi now. You could nip out for 5 minutes to transfer the money then come back and pick up hte bike.