Upgrade implies an improvement in some way, otherwise it’s just a change so what specifically are you trying to upgrade…
– performance? (in what way?)
Ultegra will perform pretty much identically (assuming 5800 – 6800) to the 105 kit you already have, it certainly won;t make you faster, mis-shift any less or cause any measurable increase in speed.
If you want more performance then that starts with identifying what aspect isn’t performing as you’d like and then looking at solutions that will address it.
– weight?
Ultegra will be a tiny bit lighter, but if weight loss is your aim then then are better more cost effective ways to do it, finishing kit which might also improve comfort, wheels which might also have other benefits, or even SRAM/Campag instead of Shimano.
– looks?
Ultegra doesn’t really look much different, but beauty is in the eye of the beholder and all that so only you can say what you want aesthetically.
If what you actually mean is, I want to feel like I’ve upgraded, then go ahead, the only reason not to is if you can’t afford it, if you cna and it’ll make you happy then crack on 😀