I’m not a fan of insulating cavities. Many moons back I was working at a house which had just been built, insulation block inner skin, filled cavity ( fibreglass in those days ) and concrete block outer skin. The roof was on and complete, windows in and heating had just been comissioned. The outer block skin was due to be rendered the following week. We had high wind and torrential rain day I was there and withinn 3 hours of the rain starting, water which was being driven at the unrendered blockwork, was being literally “sucked” through the blocks, the insulation and began running down the unplastered inner skin.
In this case, is the room heated ? I reckon it doesn’t vent well enough.
Poor mans dehumidifier is to place a pot of salt on the window cill, say a margarine tub, half filled with salt and the lid put back on with a load of holes punched in it, you’ll need to change it often, but watch just how fast that salt absorbs the moisture.