The gearing will probably be based around the alfines 1:1 gear (about mid range right)
So (32/16=2)x(26/21=1.23)=2.47
Near as damn it a 2.5:1 ratio… Quite close to 32:13
For simplicity sake I would keep the 32-16 primary gear and maybe look at ways to vary the second stage ratio… Maybe start at 20-16 and go from there…
I am guessing the 26t at the alfines is a special, drilled/ adapted so it can be bolted to the drive side spoke flange on the alfine?
If you’re looking to replace the alfine with some sort of SS hub maybe look for something in 36h with a larger flange to make machining a sprocket to suit a bit easier…
Or put a disc hub in there backwards (disc mount on the drive side, may need some re-spacing of the axle too?) and try spacing a couple of these disc mounting sprockets… on there, making sure you have a working freewheel on the rear hub..