The difference will be initially noticeable, but as with many things you soon adjust and it becomes ‘normal’…
And this:
there will be many differences and not just the head angle
Bikes being the sum of their parts and all, other factors will affect how it handles and rides.
As a “wheels on the ground” sort of rider OP having a more stable, controllable bike makes plenty of sense, slacker HA’s aren’t just for DH bikes, and DH bikes have become much slacker themselves in recent years, 66* would be quite “conservative” DH bike geometry these days I reckon…
It’s also worth noting that a sagging FS bike retains or even slackens off its angles when you put a rider onboard, HTs steepen by a degree or two… Stated figures are just an indication…