What theotherjonv said. They’re mathematically correct if the chain was somehow parallel top and bottom, but it’s not as it wraps round more than 180deg and converges towards the back of the bike (on a singlespeed, with a mech it probably wraps less than 180 and diverges).
Also, even ’round’ chainrings seldom are, or they are but it’s hard to mount them perfectly concentric on the cranks, so there’s always a high spot, which will probably compound an oval rings problems.
You don’t need it bar tight to singlespeed, infact it should be as slack as possible before it falls off.
Assuming it’s a hardtail (SS’ing a FS is going to be a non starter) then stick it in whateve gear gives the best chainline and see if that gives a good place to break+join the chain, if not, move up/down one so that the tension is about right. It should work as I’ve run old ramped sprockets in SS setups when I’ve not had the right ratio to hand, although that’s with a tensioner (or EBB etc), but the ramping won’t help as modern sprockets really are designed to throw the chain off to facilitate shifting.