They are designed to be single use. You can get them apart, particularly if you have the quick link pliers, but they’re not designed to be reused. They’re already the weakest part of the chain, no point making them weaker IMO when KMC and Connex ones are actually designed to be reusable.
You can interchange road/MTB Shimano chains, shifting quality may be slightly diminished, but it’ll work fine. Equally you can use other brands of chain with no issues. I’ve used SRAM, KMC and Shimano, personally think the SRAM are overpriced, Shimano seem to outlast them, currently got an X10SL, which is light, but like the X9SL they don’t last.