What thermostat are you running? I guess it's new if the boiler is but ours made a big difference.
We had a combi with standard 'on/off' bi-metal thermostat and 24 hour timer on the boiler.
Swapped it for a 7 day digital thermostat with hi/lo settings. Stuck boiler on constant and let the thermostat handle it all.
Before house would get hot, overshoot the set temp, get really hot, turn off, get really cold, fire up, run 100% into overshoot again. House got hot/cold/hot/cold. Then at night, it was off or boiling.
The boiler runs less hard and the house is a much more even temp. 19 degrees during the day, 14 degrees at night.
If the room temp is above the 'stat setting, the boiler in 'on' but not running. Less heat change uses less fuel. Imagine cruising at 70 compared to dropping back to 60, accelerating up to 80, dropping back to 60 again, accelerating…
Our gas usage is tracked monthly and our bills dropped significantly. The year on year usage shows a clear step down right when I fitted the new 'stat.
Lovely.
Just need to reprogram it so 19C displays as 22C and the Mrs. will be happy too!