Rover V8’s have a timing chain … first fitted to the rover P5 in 1967 … even then it was a derivative of a buick engine so goes back before that.
Pros and cons to each I suppose. Belts are lighter and cheaper, very efficient, but more likely to wear to the point of destruction. Chains perhaps stronger, but heavier, and although they’ll stretch and so affect timing, less likely to snap completely as a result of plain wear.
Changing a chain in most cases is not necessarily a technically difficult job. the difficult comes from getting to the fekker to be able to change it. There is so much stuff tacked onto the side of an engine bloc these days, it takes hours to get it off and out of the way before you can even see the chain.
Personally, I prefer chains to belts.