Right, if those devices charge over USB, then what you need is 5v DC out. The two panels in series give over 7v (roughly what you need to feed the regulator to get a stable 5v out) in any reasonable light, like somewhat overcast daytime. The limiting factor is the current. My hacked thing above will charge about 700mA at full chat(bright light, no clouds) so you’re looking at 3 hours for the Samsung and 6 hours for the Motorola (are you sure it’s 4000mA?!) Really it’s best used all day, I mean left plugged in to the phone.
That’s a lot of battery capacity there, and two devices means more power lost in the recharge. I would suggest you just use the one device, less lost energy.
I’m not quite sure what the other bits you wrote mean, but you can only charge lithium batteries with a charging circuit, charging the direct will ruin then. Let the phone do it.
Tbh, it’s going to be a real pain with all that gear, I’d been thinking you just meant 2x phones and that was it.
You could also use the panels to charge up the power bank, but each extra layer decreases the efficiency.
If you want, post back and I’ll see if I can help more, but IMHO u really need to simplify the setup, or go with the 16,000mAh bank, it’s a bit of a bargain… But when it’s flat it’s flat!